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Pigments

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楼主
发表于 4-26-2018 14:06:27 | 只看该作者 回帖奖励 |倒序浏览 |阅读模式
本帖最后由 choi 于 4-26-2018 14:09 编辑

Zach Schonbrun, The Quest for the Next Billion-Dollar Color. The world's first new blue pigment in two centuries is finally on sale, nine years after it was discovered. Now its creator wants to find the first truly safe, stable, bright red. Bloomberg BusinessWeek, Apr 23, 2018 (one of feature stories).
https://www.bloomberg.com/featur ... billion-dollar-red/

Note:
(a) "Mas Subramanian[, 64] * * * glances at a cluster of widemouthed jars containing powders in every color of the rainbow, save one [bright red]. He's got OYGBIV. * * * During his nine-year [since 2009] sojourn into the strange, finicky realm of color, Subramanian, a materials science professor at Oregon State University at Corvallis [1868- ], has grown infatuated with a form of chemistry that he, like many of his peers, once considered decidedly low-tech. His renown derives from his accidental creation, in 2009, of a new pigment, a substance capable of imparting color onto another material. YInMn blue (pronounced YIN-min) is an amalgam of yttrium, indium oxide, and manganes * * * YInMn was the first blue pigment discovered in more than 200 years.  It isn't only the exotic blueness that has excited the color industry, but also the other hues the pigment can generate. Subramanian soon realized that by adding copper, he could make a green. With iron, he got orange. Zinc and titanium, a muted purple.
(i) Mas Subramanian. Department of Chemistry, Oregon State University, undated
chemistry.oregonstate.edu/content/mas-subramanian
("BS University of Madras, India (1975)
MS University of Madras, India (1977)
PhD Indian Institute of Technology, Madras, India (1981)
Post-Doctoral Fellow, Texas A&M University (1982-84)
Milton Harris Professor of Materials Science, Oregon State Univ (2006 - )"

Both University of Madras (1857- ; public) and IIT Madras (1959- ; public) are based in Chennai.
(A) Chennai
https://en.wikipedia.org/wiki/Chennai
(capital of the Indian state of Tamil Nadu [literally 'The Land of Tamils' or 'Tamil Country': en.wikipedia.org]; section 1 Etymology)

Quote section 1: "According to some sources, Madras was derived from Madraspattinam, a fishing-village north of Fort St George. However, it is uncertain whether the name was in use before the arrival of Europeans. The British military mapmakers believed Madras was originally Mundir-raj or Mundiraj." (citations omitted)

Due to this uncertainty (of origin), Madras's meaning is murky.

(B) nadu
https://en.wikipedia.org/wiki/Nadu
(Nadu a term used to mean land, place, domicile etc. in South Indian languages)
(C) Hazeeda Vijayakumar, Story of Madras. Chennai: The Hindu (newspaper), Aug 20, 2013
http://www.thehindu.com/features ... /article5041625.ece
(ii)
(A) Mas Subramanian lists his name in scientific publications as "M A Subramanian." It is obvious that Mas is the acronym of his whole name -- much the same as Jeb Bush (former Florida governor and younger brother of George W Bush) whose birth -- and official -- name is John Ellis Bush.
(B) Subramanian
https://en.wikipedia.org/wiki/Subramaniam
(etymology [and hence the meaning] unknown)
(iii) pronunciations
(A) Chennai
https://www.merriam-webster.com/dictionary/Chennai
(B) madras
https://www.merriam-webster.com/dictionary/madras

is a cloth
https://en.wikipedia.org/wiki/Madras_(cloth)
(photo)
that was named after City of Madras (former name of Chennai).
(iv) ROYGBIV (red to indigo and violet) indicates colors of visible light whose wavelengths span 400 to 700 nm.
(v)
(A) Corvallis, Oregon
https://en.wikipedia.org/wiki/Corvallis,_Oregon
(map; section 1 History; section 1.2 Name change: Corvallis," from the Latin meaning "heart of the valley)

is wholly on the left bank of Willamette River.
https://en.wikipedia.org/wiki/Willamette_River
(pronunciation; map; "The name Willamette is of indigenous origin, deriving from the French pronunciation of the name of a Clackamas [a tribe name] Native American village")
(B) Latin-English dictionary:
* cor (noun neuter):
"1 : (anatomy) heart
2 : (figuratively) soul, mind"
https://en.wiktionary.org/wiki/cor
* vallis (noun feminine): "valley"  (The English noun valley ultimately comes from this Latin word.)
https://en.wiktionary.org/wiki/vallis
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沙发
 楼主| 发表于 4-26-2018 14:12:56 | 只看该作者
本帖最后由 choi 于 4-26-2018 14:16 编辑

(b) "The world lacks a great all-around red. Always has. We've made do with alternatives that could be toxic or plain gross. The gladiators smeared their faces with mercury-based vermilion [mercury sulfide whose chemical formula is HgS; 朱砂]. Titian painted with an arsenic-based mineral called realgar. The British army’s red coats were infused with crushed cochineal beetles [which, in Latin America, feeds on cacti]. For decades, red Lego bricks contained cadmium, a carcinogen."
(i) all-around (adj)
https://www.merriam-webster.com/dictionary/all-around
(ii) Titian
https://en.wikipedia.org/wiki/Titian
(c 1488/1490 – 1576)
(iii)
(A) realgar
https://en.wikipedia.org/wiki/Realgar
(Its name comes from the Arabic)
(B) realgar
https://www.merriam-webster.com/dictionary/realgar
(pronunciation)

(c) "More than 200 natural and synthetic red pigments exist today, but each has issues with safety, stability, chromaticity, and/or opacity. Red 254 ['which is worth an estimated $300 million annually'], aka Ferrari red, for example, is safe and popular, but it's also carbon-based, leaving it susceptible to fading in the rain or the heat. * * * One red is stable, nontoxic, and everlasting: iron oxide, or red ocher [Fe2O3], the ruddy clay found in Paleolithic cave paintings. 'It's just not bright in the way that people want' * * * The most commercially successful blue, phthalocyanine * * * A single one, titanium dioxide [color white], accounts for almost two-thirds of the pigments produced globally; valued at about $13.2 billion
(i) chromaticity (n): "the quality of colour, independent of brightness"
https://en.oxforddictionaries.com/definition/chromaticity
(ii)
(A) Pigment Red 254. PubChem, undated
https://pubchem.ncbi.nlm.nih.gov/compound/Pigment_Red_254
(both molecular formula and 2D structure)
(B) Michael Norman, The story behind Pigment Red 254, nicknamed 'Ferrari Red.' Cleveland, OH: The Plain Dealer, Oct 23, 2007 (blog)
https://blog.cleveland.com/pdextra/2007/10/pollock_cuts.html
("the 1983 Ciba-Geigy patent")
(iii) phthalocyanine (n; etymology: International Scientific Vocabulary phthalic acid + -o- + cyanine)
https://www.merriam-webster.com/dictionary/phthalocyanine
(pronunciation)
(iv) titanium dioxide. PubChem, undated
https://pubchem.ncbi.nlm.nih.gov ... ection=2D-Structure
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板凳
 楼主| 发表于 4-26-2018 14:14:35 | 只看该作者
(d) "Subramanian entered the annals of pigment lore even though he wasn't looking for a pigment or even mixing ingredients thought capable of making a distinctive color. He and his co-investigators were after electronics—specifically a multiferroic, a material that's both electrically and magnetically polarized, which is useful for computing. The yttrium [Y;钇] began as pale white, the indium [In; 铟] oxide black, and the 钇 锰 a bilious yellow. One of Subramanian’s postdoctoral students, Andrew Smith, ground them to gray [note the color before baking, which is shown in a photo of this article], placed the blend in a small dish, and stuck it in a furnace heated to 2,200F. Twelve hours later, out of the oven came a deep, vibrant, intoxicating blue. It was so radiant, so fantastic, it appeared almost extraterrestrial—the ripest Venusian blueberry, cleaned, polished, and glowing from within. * * * Shepherd Color Co sent representatives to Oregon State within a week of the paper's publication * * * Shepherd won the exclusive license in 2015 * * * (The company declined to disclose the terms of the deal.) Last September, eight years after Subramanian's discovery, the US Environmental Protection Agency finally approved YInMn for commercial sale in industrial coatings and plastics. Shepherd swiftly went to market. * * * Shepherd lists YInMn blue at $1,000 per kilogram, by far its most expensive pigment."
(i) I am clueless why Prof Subramanian says 钇 is yellow.
(ii) "Pure manganese is reactive, burns in oxygen, rusts in water": from the Web.
(iii) Andrew E Smith, PhD is presently Product Engineering Manager, at Uniform Color Company in Michigan.
(iv) "YInMn Blue [trademark] is a new pigment from Shepherd Color" Company based in Cincinnati, OH: from company website.
(v) About "Venusian blueberry." This article is the source of the term in the Web. No doubt Venusian os adjective of Venus. But what does Venus mean in this context? U can only guess that it is a swimwear company, which does have blueberry bikini.

(e) "Blue is one of nature's most abundant tones, but it's proved hard for human hands to create. When the ancient Egyptians tried to replicate the deep, oceanic tone of ultramarine to adorn tombs, papyrus, and art, they wound up with something more like turquoise [for Egyptian blue, see next posting]. During the Renaissance, ultramarine could be costlier than gold, because the lapis lazuli from which it derives was mined in remote Afghanistan. (Michelangelo nevertheless scored some for the Sistine Chapel ceiling.) The first modern synthetic pigment, Prussian blue, or ferric ferrocyanide, wasn't discovered until the early 18th century, by a German chemist trying to make red. Since then, many common blues (cerulean, midnight, aquamarine, smalt) have contained traces of cobalt, a suspected carcinogen. * * * In paint, cadmium [for red color] had long been considered safe and durable; its brilliance enlivened the works of Monet, van Gogh, and Munch"
(i) Prussian blue
https://en.wikipedia.org/wiki/Prussian_blue
(ii) Edvard Munch
https://en.wikipedia.org/wiki/Edvard_Munch
(1863 – 1944; Norwegian; most famous for The Scream (1893) )
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4#
 楼主| 发表于 4-26-2018 14:16:18 | 只看该作者
(f) "Patent No 8,282,728 is for something potentially far more valuable than YInMn itself. In fact, it only briefly mentions 'intense blue color.' Subramanian's true invention was the crystal structure—or the atomic arrangement—of the material, called trigonal bipyramidal coordination. The manganese imparts the blueness, and by adjusting its proportion in the compound, you can lighten or darken its tint."
(i) trigonal bipyramidal molecular geometry
https://en.wikipedia.org/wiki/Tr ... _molecular_geometry
(A) Read sentence 1 and view the schematic, it is hard to imagine what the crystal looks like --even if you click "triangular dipyramid" in sentence 1. So, proceed to (e)(ii).
(B) schematic (n): "a schematic drawing or diagram"
www.merriam-webster.com/dictionary/schematic
(ii) C Ophardt, Trigonal Bipyramid Molecular Geometry. Chemistry Department, Elmhurst College (private; Elmhurst, Illinois), 2003/
https://chemistry.elmhurst.edu/vchembook/220trigbipy.html

(g) Subramanian said of his wife: " 'We went to the Guggenheim [in SoHo, Manhattan]' * * * he stopped in front of Kandinsky's Blue Mountain and gawked at the ultramarine used to paint the arresting peak."
(i) list of Guggenheim Museums
https://en.wikipedia.org/wiki/List_of_Guggenheim_Museums
(ii)
(A) Wassily Kandinsky
https://en.wikipedia.org/wiki/Wassily_Kandinsky
(1866 (Moscow) – 1944 (near Paris); The Blue Mountain (1908–1909) )
(B) Vasily Kandinsky Blue Mountain - Guggenheim
https://www.guggenheim.org/artwork/1844

The museum says for its system, my computer in a library is not supported and can not view. But many other places in the Web offer a peek.
(iii) ultramarine
https://en.wikipedia.org/wiki/Ultramarine
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